DIRECT STEREOSPECIFIC CONVERSION OF ACYCLIC VICINAL DIOLS INTO OLEFINS AND ITS REACTION-MECHANISM

被引：2
|
作者：
OHRUI, H
NAGIHASHI, K
MEGURO, H
机构：
[1] Department of Food Chemistry, Faculty of Agriculture, Tohoku University, Sendai 981, Tsutsumidori-Amamiya
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1992年 / 56卷 / 11期
关键词：
D O I：
10.1271/bbb.56.1721
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A direct stereospecific conversion of acyclic vicinal diols into olefins was developed, and a study on the reaction mechanism elucidated that the reaction was s-cis with respect to the hydroxy groups and s-trans with respect to the iodo and hydroxy groups of the intermediate iodo alcohols.
引用
收藏
页码：1721 / 1724
页数：4
相关论文
共 50 条
  • [41] Direct evidence of a radical mechanism in the addition reaction of iododifluoroesters to olefins by spin trapping
    Julià, L
    Bosch, MP
    Rodriguez, S
    Guerrero, A
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (17): : 5098 - 5103
  • [42] Methylation of olefins with ketene in zeotypes and its implications for the direct conversion of syngas to light olefins: a periodic DFT study
    Wang, Chuan-Ming
    Wang, Yang-Dong
    Xie, Zai-Ku
    CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (17) : 6644 - 6649
  • [43] Palladium-catalyzed stereospecific epoxide-opening reaction of γ,δ-epoxy-α,β-unsaturated esters with an alkylboronic acid leading to γ,δ-vicinal diols with double inversion of the configuration
    Hirai, A
    Yu, XQ
    Tonooka, T
    Miyashita, M
    CHEMICAL COMMUNICATIONS, 2003, (19) : 2482 - 2483
  • [44] On the reaction mechanism of MnOx/SAPO-34 bifunctional catalysts for the conversion of syngas to light olefins
    Coudercy, Christophe
    L'hospital, Valentin
    Checa, Ruben
    Le Valant, Anthony
    Afanasiev, Pavel
    Loridant, Stephane
    CATALYSIS SCIENCE & TECHNOLOGY, 2021, 11 (24) : 7844 - 7849
  • [45] PHOTOCHEMICAL REACTION OF 2-ALKOXY-1,4-NAPHTHOQUINONES WITH OLEFINS .3. RE-EXAMINATION OF STRUCTURES OF PHOTOADDITION COMPOUNDS AND REACTION-MECHANISM
    OTSUKI, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1976, 49 (09) : 2596 - 2605
  • [46] SOME REMARKS ON REACTION-MECHANISM AND KINETIC RATE CONSTANTS FOR PENTACYANOCOBALTATE (II)-CATALYZED HYDROGENATION OF OLEFINS USING ITERATIVE SIMULATION TECHNIQUE
    OHKUBO, K
    TSUCHIHASHI, K
    IKEBE, H
    SAKAMOTO, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (04) : 1114 - 1117
  • [47] PRIMARY KINETIC SALT EFFECT ON THE RATE CONSTANTS OF CHAIN REACTIONS AND ITS RELATION TO THE REACTION-MECHANISM
    ESPENSON, JH
    RYAN, DA
    JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (24): : 3658 - 3660
  • [48] INVESTIGATION OF KINETICS AND REACTION-MECHANISM FOR SULFURATION OF THIOPHENE AND ITS DERIVATIVES WITH COMPLEXES OF SULFUR-TRIOXIDE
    SHUSTAREVA, TK
    DRUZHININA, VY
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1986, (01): : 34 - 39
  • [49] REACTION-MECHANISM OF RAT-LIVER GLYOXALASE 1 AND ITS INHIBITION BY MS-3
    KURASAWA, S
    TAKEUCHI, T
    UMEZAWA, H
    AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1976, 40 (03): : 559 - 566
  • [50] REACTION-MECHANISM OF INITIAL DEHYDRATION OF ZIRCONIUM OXIDE CHLORIDE OCTAHYDRATE IN ITS THERMAL-DECOMPOSITION
    KIKUCHI, M
    NIPPON KAGAKU KAISHI, 1974, (12) : 2346 - 2350
12345