DIRECT STEREOSPECIFIC CONVERSION OF ACYCLIC VICINAL DIOLS INTO OLEFINS AND ITS REACTION-MECHANISM

被引：2
|
作者：
OHRUI, H
NAGIHASHI, K
MEGURO, H
机构：
[1] Department of Food Chemistry, Faculty of Agriculture, Tohoku University, Sendai 981, Tsutsumidori-Amamiya
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1992年 / 56卷 / 11期
关键词：
D O I：
10.1271/bbb.56.1721
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A direct stereospecific conversion of acyclic vicinal diols into olefins was developed, and a study on the reaction mechanism elucidated that the reaction was s-cis with respect to the hydroxy groups and s-trans with respect to the iodo and hydroxy groups of the intermediate iodo alcohols.
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页码：1721 / 1724
页数：4
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