INITIAL DISTRIBUTIONS OF CD(3P0,1,2) ELECTRONIC STATES IN THE COLLISIONAL DEACTIVATION OF CD(1P1) BY ALKANE HYDROCARBONS

被引：13

作者：

BRECKENRIDGE, WH

MALMIN, OK

机构：

[1] Department of Chemistry, University of Utah, Salt Lake City

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)87213-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The initial distributions of Cd(3P0,1,2) electronic states have been determined for the E-to-V,R process, Cd)1P1) + RH → Cd(3P0,1,2) + RH. The Cd(3P0,1,2) distributions vary smoothly with n in the alkane CnH2n+2 series, from non-statistical for CH4 (with Cd(3P2) favored) to statistical for the C4 and C5 hydrocarbons, with neopentane an exception. © 1979.

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页码：341 / 346

页数：6

相关论文

共 14 条

[1] QUENCHING OF EXCITED CADMIUM P-1(1) ATOMS BY SEVERAL MOLECULES - CROSS-SECTIONS AND CHEMICAL AND PHYSICAL EXIT CHANNELS [J].

BRECKENRIDGE, WH ;

RENLUND, AM .

JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (13) :1474-1484

[2] DETERMINATION BY RESONANCE RADIATION FLASH-PHOTOLYSIS OF ABSOLUTE REACTION-RATES OF EXCITED CADMIUM(53P0,1) ATOMS WITH SEVERAL GASES [J].

BRECKENRIDGE, WH ;

BROADBENT, TW ;

MOORE, DS .

JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (13) :1233-1242

[3] REACTION OF EXCITED CADMIUM P-3(J) AND CADMIUM P-1(1) ATOMS WITH H-2 HD, AND D-2 - QUENCHING CROSS-SECTIONS AND CDH(CDD) YIELDS [J].

BRECKENRIDGE, WH ;

RENLUND, AM .

JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (13) :1484-1491

[4] REACTION OF EXCITED CADMIUM (P-3J) ATOMS WITH ALKANE HYDROCARBONS - QUENCHING CROSS-SECTIONS AND PRIMARY CDH YIELDS [J].

BRECKENRIDGE, WH ;

RENLUND, AM .

JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (03) :303-309

[5] LASER EXCITATION OF CD(P-1(1)) - ABSOLUTE QUENCHING CROSS-SECTIONS AND BRANCHING RATIOS FOR THE PROCESS - CD(P-1(1)+M-]CD(P-3(J))+M [J].

BRECKENRIDGE, WH ;

DONOVAN, RJ ;

KIMMALMIN, O .

CHEMICAL PHYSICS LETTERS, 1979, 62 (03) :608-614

[6] RAPID PUMP-AND-PROBE LASER TECHNIQUE FOR DETERMINING STATE-RESOLVED PRODUCT DISTRIBUTIONS [J].

BRECKENRIDGE, WH ;

MALMIN, OK ;

NIKOLAI, WL ;

OBA, D .

CHEMICAL PHYSICS LETTERS, 1978, 59 (01) :38-42

[7]

BRECKENRIDGE WH, UNPUBLISHED

[8]

Forst W., 1973, THEORY UNIMOLECULAR

[9] POPULATION OF POTASSIUM FINE-STRUCTURE STATES 42P1/2 AND 42P3/2 IN COLLISIONS WITH MERCURY AND SEVERAL MOLECULES [J].

KEMPTER, V ;

KOCH, W ;

SCHMIDT, C .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1974, 7 (11) :1306-1311

[10]

LEVINE RD, 1977, CHEM BIOCH APPLICATI, V2