INITIAL DISTRIBUTIONS OF CD(3P0,1,2) ELECTRONIC STATES IN THE COLLISIONAL DEACTIVATION OF CD(1P1) BY ALKANE HYDROCARBONS

被引:13
作者
BRECKENRIDGE, WH
MALMIN, OK
机构
[1] Department of Chemistry, University of Utah, Salt Lake City
关键词
D O I
10.1016/0009-2614(79)87213-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The initial distributions of Cd(3P0,1,2) electronic states have been determined for the E-to-V,R process, Cd)1P1) + RH → Cd(3P0,1,2) + RH. The Cd(3P0,1,2) distributions vary smoothly with n in the alkane CnH2n+2 series, from non-statistical for CH4 (with Cd(3P2) favored) to statistical for the C4 and C5 hydrocarbons, with neopentane an exception. © 1979.
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页码:341 / 346
页数:6
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