Crystal Structure of (E)-2-(3,3,3-trifluoroprop-1-en-1-yl)aniline

被引：0

作者：

Kubono, Koji ^{[1
]}

Tani, Keita ^{[1
]}

Omote, Masaaki ^{[2
]}

Ogawa, Futa ^{[2
]}

Matsumoto, Taisuke ^{[3
]}

机构：

[1] Osaka Kyoiku Univ, Div Nat Sci, Kashiwara, Osaka 5828582, Japan

[2] Setsunan Univ, Fac Pharmaceut Sci, Hirakata, Osaka 5730101, Japan

[3] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷

关键词：

crystal structure; 3,3,3-trifluoroprop-1-en; aniline; hydrogen bonding;

D O I：

10.1107/S2056989018012756

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecule of the title compound, C9H8F3N, adopts an E configuration with respect to the C=C double bond. The dihedral angle between the benzene ring and the prop-1-enyl group is 25.4 (3)degrees. In the crystal, molecules are linked via pairs of N-H center dot center dot center dot F hydrogen bonds into inversion dimers with an R-2(2)(16) ring motif. The dimers are linked by C-H center dot center dot center dot N hydrogen bonds, forming a ribbon structure along the b-axis direction. The ribbons are linked by N-H center dot center dot center dot pi and C-H center dot center dot center dot pi interactions, generating a three-dimensional network.

引用

页码：1448 / +

页数：7

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