CARBONYL HALIDES OF GROUP 6 TRANSITION METALS .8. PARAMAGNETIC AND DIAMAGNETIC DICARBONYL DERIVATIVES OF MOLYBDENUM(2)

被引：26

作者：

COLTON, R

RIX, CJ

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1968年 / 21卷 / 05期

关键词：

D O I：

10.1071/CH9681155

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes of the general formula Mo(CO)2L2X2 (L = pyridine (py), 2, 2′ dipyridyl (dipy), 1, l0-phenanthroline (phen); X = Cl, Br) have been isolated. The pyrldine derivatives are yellow monomeric compounds which are paramagnetic, but the complexes with dipy and phen contain diamagnetic seven-coordinate cations and are correctly formulated as [Mo(CO)2L2X]+X−. Conductance, infrared, magnetic, and electron spin resonance studies have been carried out. © 1968 CSIRO. All rights reserved.

引用

页码：1155 / &

共 7 条

[1] UBER DIE REAKTIONEN DER DICARBONYL-BIS(BIPYRIDYL-(2,2'))-BZW . DICARBONYL-BIS(1,10-PHENANTHROLIN)-VERBINDUNGEN DES NULLWERTIGEN MOLYBDANS UND WOLFRAMS MIT JOD [J].