INFRARED AND RAMAN STUDIES OF HETEROCYCLIC COMPOUNDS .2. INFRARED SPECTRA AND NORMAL VIBRATIONS OF BENZIMIDAZOLE AND BIS-(BENZIMIDAZOLATO)-METAL COMPLEXES

被引：130

作者：

CORDES, MM

WALTER, JL

机构：

[1] Department of Chemistry, Radiation Laboratory1 1 The Radiation Laboratory is operated by the University of Notre Dame, contract with the Atomic Energy Commission. This is document No. COO-38-557. Acknowledgement is also, Notre Dame, IN

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 09期

关键词：

D O I：

10.1016/0584-8539(68)80165-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The infrared spectra of benzimidazole and some of its metal complexes were obtained from 4000 to 33 cm-1. The bands in benzimidazole are tentatively assigned by comparisons with spectra of 1,2 d2-benzimidazole, the metal complexes, N-iodobenzimidazole and other aromatic and heteroaromatic systems. A complete normal coordinate calculation was carried out on benzimidazole, and the metal-nitrogen interactions in the polymer complexes were studied as five body problems. For comparison, five body calculations were also studied for the metal complexes of Imidazole. © 1968.

引用

页码：1421 / &

共 30 条

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