INFRARED AND RAMAN STUDIES OF HETEROCYCLIC COMPOUNDS .2. INFRARED SPECTRA AND NORMAL VIBRATIONS OF BENZIMIDAZOLE AND BIS-(BENZIMIDAZOLATO)-METAL COMPLEXES

被引：130
作者：
CORDES, MM
WALTER, JL
机构：
[1] Department of Chemistry, Radiation Laboratory1 1 The Radiation Laboratory is operated by the University of Notre Dame, contract with the Atomic Energy Commission. This is document No. COO-38-557. Acknowledgement is also, Notre Dame, IN
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 09期
关键词：
D O I：
10.1016/0584-8539(68)80165-5
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The infrared spectra of benzimidazole and some of its metal complexes were obtained from 4000 to 33 cm-1. The bands in benzimidazole are tentatively assigned by comparisons with spectra of 1,2 d2-benzimidazole, the metal complexes, N-iodobenzimidazole and other aromatic and heteroaromatic systems. A complete normal coordinate calculation was carried out on benzimidazole, and the metal-nitrogen interactions in the polymer complexes were studied as five body problems. For comparison, five body calculations were also studied for the metal complexes of Imidazole. © 1968.
引用
收藏
页码：1421 / &
相关论文
共 30 条
123