SYNTHESES AND REACTIONS OF ACYCLIC AND CYCLIC CARBENE COMPLEXES CIS-[MI(=CMENHME)(CO)2(ETA-C5H5)](M=MO OR W) AND CIS-[MI(=C(CH2)NNME)(CO)2(ETA-C5H5)](M=MO,N=3 OR 4-M=W,N=3) OBTAINED THROUGH ALKYL MIGRATION TO METHYL ISOCYANIDE COORDINATED TO MOLYBDENUM OR TUNGSTEN - X-RAY STRUCTURE OF CIS-[MOI(=C(CH2)3NME)-(CO)2(ETA-C5H5)]O

被引：21

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

OSBORN, VA ^{[1
]}

WINTER, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1986年 / 10期

关键词：

D O I：

10.1039/dt9860002127

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2127 / 2135

页数：9

共 50 条

[21] REACTIONS OF COORDINATED LIGANDS .28. THE REACTION OF NUCLEOPHILIC-REAGENTS WITH THE CATIONIC BIS(ACETYLENE) MOLYBDENUM COMPLEXES [MO(CO) (RC2R')2 (ETA-C5H5)][BF4] - X-RAY CRYSTAL-STRUCTURES OF [MO(C(ME)=C(ME)C(O)C(ME)=CHME)(CO)2(ETA-C5H5)] AND [MO(ETA-3-ETA-2-HBU-TERTC-CH-C-O-C(O)C(BU-TERT)=CH)(CO)(ETA-C5H5)]C2
ALLEN, SR
GREEN, M
NORMAN, NC
PADDICK, KE
ORPEN, AG
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[22] REACTIONS OF THE METALLABROMOALKANE [MO((CH2)3BR)(CO)3(ETA-C5H5)] AND THE CARBENE COMPLEXES TRANS-[MOI(=C(CH2)3O)(CO)2(ETA-C5H4R)](R=H OR ME) WITH LI(BET3H) - THE SYNTHESIS (R=H OR ME) AND X-RAY STRUCTURE (R=ME) OF [MO(CH(CH2)3O)(CO)2(ETA-C5H4R)] CONTAINING AN UNUSUAL OXYGEN MOLYBDENUM DONOR INTERACTIONH
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[23] THE SYNTHESIS AND H-1-NMR STUDY OF VINYL ORGANOMETALLIC MONOMERS - (ETA-5-C5H4CH=CH2)M(CO)2(NO) (M=CR, MO, W) AND (ETA-5-C5H4CH=CH2)M(CO)2 (M=CO, RH, IR)
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[24] CHEMISTRY OF PHOSPHIDO-BRIDGED DIMOLYBDENUM COMPLEXES .6. THE INSERTION OF ALLENE INTO COORDINATED (MU-VINYL AND ETA-3-ALLYL LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [MO2(ETA-C5H5)2(MU-PME2)(ETA-3-CH2C(CH2)C(ME)=CH2)(CO)3] AND [MO2(ETA-C5H5)2(MU-ETA-5-CH2C(CH2)C(ME)=CH2)(MU-PME2)(CO)2]
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[25] REACTION OF THE ALKYLIDYNE COMPLEX [W=CR)(CO)2(ETA-C5H5)] WITH PHPH2 - SYNTHESIS AND X-RAY STRUCTURES OF THE COMPLEXES [W(CHRPPH2)(CO)2(ETA-C5H5)] AND [W(CHRCOOPPH2)(PHPH2)(CO)(ETA-C5H5)] (R=C6H4ME-4)
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[26] Thermal transformation of cis- and trans-[{Mo(CO)(3)H}(2){mu-eta(5):eta(5)-C5H3(SiMe(2))(2)C5H3}] into [{Mo(CO)(3)}(2){mu-eta(5):eta(5)-C5H4(SiMe(2)SiMe(2))-C5H4}](MO-MO) promoted by hydride migration
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[27] CLEAVAGE OF M=C (M = MO OR W) BONDS IN THE FORMATION OF THE COMPLEXES [FE2M(MU-C2R)(CO)8(ETA-C5H5)] - X-RAY CRYSTAL-STRUCTURE OF [FE2W(MU-C2C6H4ME-4)(CO)8(ETA-C5H5)]
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[28] THE CHEMISTRY OF [NIM(CO)4(ETA-C5H5)(ETA-C5H4ME)] (M = MO, W) AND SOME REACTIONS WITH ALKYNES
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[29] Thermal Transformation of cis- and trans-[{Mo(CO)3H}2{ae-eta5 :eta5$ MIN@C5H3(SiMe2)2C5H3}] into [{Mo(CO)3}2{ae-eta5:eta5$M IN@C5H 4(SiMe2SiMe2)C5H4}](Mo-Mo) Promoted by Hydride Migration
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[30] REACTION OF [WME(CO)3(ETA-C5H5)] WITH LIBHET3 - FORMATION AND REACTIONS OF THE ANIONIC FORMYL TRANS-[W(CHO)ME(CO)2(ETA-C5H5)] AND THE ANIONIC HYDRIDO ACYL TRANS-[WH(COME)(CO)2(ETA-C5H5)]
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