SYNTHESES AND REACTIONS OF ACYCLIC AND CYCLIC CARBENE COMPLEXES CIS-[MI(=CMENHME)(CO)2(ETA-C5H5)](M=MO OR W) AND CIS-[MI(=C(CH2)NNME)(CO)2(ETA-C5H5)](M=MO,N=3 OR 4-M=W,N=3) OBTAINED THROUGH ALKYL MIGRATION TO METHYL ISOCYANIDE COORDINATED TO MOLYBDENUM OR TUNGSTEN - X-RAY STRUCTURE OF CIS-[MOI(=C(CH2)3NME)-(CO)2(ETA-C5H5)]O

被引：21

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

OSBORN, VA ^{[1
]}

WINTER, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1986年 / 10期

关键词：

D O I：

10.1039/dt9860002127

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2127 / 2135

页数：9

共 29 条

[1] REACTIONS OF METALLABROMOALKANES [M((CH2)NBR)(CO)3(ETA-C5H5)] (M=MOORW,N=3OR4) WITH TRANSITION-METAL ANIONS - DIMETALLAALKANE AND CYCLIC CARBENE COMPLEX-FORMATION - CRYSTAL AND MOLECULAR-STRUCTURES OF [(ETA-C5H5)(OC)3MO((CH2)4)MO(CO)3(ETA-C5H5)] AND [(ETA-C5H5)(OC)3MOW(CO)2(C-O-(CH2)2CH2)(ETA-C5H5)] [J].

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[2] REACTIONS OF THE METALLABROMOALKANE [MO((CH2)3BR)(CO)3(ETA-C5H5)] AND THE CARBENE COMPLEXES TRANS-[MOI(=C(CH2)3O)(CO)2(ETA-C5H4R)](R=H OR ME) WITH LI(BET3H) - THE SYNTHESIS (R=H OR ME) AND X-RAY STRUCTURE (R=ME) OF [MO(CH(CH2)3O)(CO)2(ETA-C5H4R)] CONTAINING AN UNUSUAL OXYGEN MOLYBDENUM DONOR INTERACTIONH [J].

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[3] AN UNUSUAL MOLYBDENUM-OXYGEN INTERACTION IN THE PRODUCT FROM REACTION OF MO([CH2]3BR)(CO)3(ETA-C5H4R) (R = H, ME) WITH LIET3BH - SYNTHESIS AND X-RAY STRUCTURE OF MO(CO)2(ETA-2-CH.O.[CH2]2CH2)(ETA-C5H4ME) [J].

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[4]

ADAMS H, 1984, J ORGANOMET CHEM, V284, pC1

[5]

ADAMS RD, 1976, INORG CHEM, V15, P169, DOI 10.1021/ic50155a036

[6] ISOCYANIDE INSERTION REACTIONS .1. IMPORTANCE OF ETA2-IMINOACYL LIGANDS AS INTERMEDIATES [J].

ADAMS, RD ;

CHODOSH, DF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) :6544-6550

[7] ISOCYANIDE INSERTION REARRANGEMENTS AND THEIR BONDING TO TRANSITION-METAL ATOMS [J].

ADAMS, RD ;

CHODOSH, DF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (17) :5391-5393

[8] ORGANOMETALLIC ANIONS CONTAINING ISONITRILE LIGANDS .2. SYNTHESIS AND REACTION CHEMISTRY OF CYCLOPENTADIENYL MOLYBDENUM DICARBONYLMETHYLISONITRILE ANION [J].

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[9]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[10] METAL CYCLIC CARBENE COMPLEXES - A MOLYBDENUM COMPLEX OF 2-OXACYCLOPENTYLIDENE - SYNTHESIS AND X-RAY STRUCTURE OF [MOL(CO)2(C4H6O)(ETA-C5H5)] [J].

BAILEY, NA ;

CHELL, PL ;

MUKHOPADHYAY, A ;

TABBRON, HE ;

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JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (04) :215-217

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