SYNTHESIS OF SUBSTITUTED CYCLOPROPANES FROM 1,3-DIOLS THROUGH THE CORRESPONDING CYCLIC SULFATES

被引：15

作者：

GUIJARRO, D ^{[1
]}

YUS, M ^{[1
]}

机构：

[1] UNIV ALICANTE,FAC CIENCIAS,DEPT QUIM ORGAN,E-03080 ALACANT,SPAIN

来源：

TETRAHEDRON | 1995年 / 51卷 / 42期

关键词：

D O I：

10.1016/0040-4020(95)00708-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of different cyclic sulfates 2 (easily prepared from the corresponding 1,3-diols 1 following the Sharpless methodology) with an excess of lithium powder and a catalytic amount of DTBB (5 mol%) leads to the corresponding substituted cyclopropanes 3 through a gamma-elimination process, the sulfate ion acting as leaving group.

引用

页码：11445 / 11456

页数：12

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