KINETICS OF OUTER-SPHERE ELECTRON-TRANSFER REACTIONS INVOLVING SYNTHETIC MODELS OF COPPER BLUE PROTEINS

被引：0

作者：

PAVLISHCHUK, VV ^{[1
]}

STRIZHAK, PE ^{[1
]}

机构：

[1] LV PISARZHEVSKII INST PHYS CHEM,KIEV,UKRAINE

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1994年 / 30卷 / 01期

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中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of outer-sphere electron-transfer reactions involving copper(II) tetrathiamacrocyclic complexes with K4[Fe(CN)6] and cyt c2+ was studied. The Marcus cross-reaction approach was applied to data obtained. The electron transfer characteristics of CuL2+/+ redox-pairs were shown to be dependent on their coordination core topology.

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页码：25 / 29

页数：5

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