KINETICS OF OUTER-SPHERE ELECTRON-TRANSFER REACTIONS INVOLVING SYNTHETIC MODELS OF COPPER BLUE PROTEINS

被引：0
|
作者：
PAVLISHCHUK, VV [1 ]
STRIZHAK, PE [1 ]
机构：
[1] LV PISARZHEVSKII INST PHYS CHEM,KIEV,UKRAINE
来源：
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1994年 / 30卷 / 01期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of outer-sphere electron-transfer reactions involving copper(II) tetrathiamacrocyclic complexes with K4[Fe(CN)6] and cyt c2+ was studied. The Marcus cross-reaction approach was applied to data obtained. The electron transfer characteristics of CuL2+/+ redox-pairs were shown to be dependent on their coordination core topology.
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页码：25 / 29
页数：5
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