ZINC-COPPER COUPLE PROMOTED C-BRANCHING IN THE CARBOHYDRATE SERIES

被引：12

作者：

BLANCHARD, P

DASILVA, AD

FOURREY, JL

MACHADO, AS

ROBERTGERO, M

机构：

[1] CNRS,INST CHIM SUBSTANCES NAT,F-91198 GIF SUR YVETTE,FRANCE

[2] UNIV FED MINAS GERAIS,DEPT QUIM,BR-31270 BELO HORIZON,MG,BRAZIL

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 52期

关键词：

ALKYL IODIDE; CARBOHYDRATE; ZINC-COPPER COUPLE; RADICAL;

D O I：

10.1016/S0040-4039(00)74719-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Efficient C-branching at 3-position of di-O-isopropylidene glucose was readily accomplished by the zinc/copper couple induced conjugate addition of its 3-iodo derivative to various activated olefins at room temperature in a protic solvent mixture.

引用

页码：8069 / 8072

页数：4

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