MOLECULAR ALUMINUM TRIHYDRIDE, ALH3 - GENERATION IN A SOLID NOBLE-GAS MATRIX AND CHARACTERIZATION BY ITS INFRARED-SPECTRUM AND AB-INITIO CALCULATIONS

被引：66

作者：

KURTH, FA

EBERLEIN, RA

SCHNOCKEL, H

DOWNS, AJ

PULHAM, CR

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

[2] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 16期

关键词：

D O I：

10.1039/c39930001302

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Broad-band photolysis of a solid noble gas matrix containing Al atoms and H-2 gives rise to the planar, monomeric AlH3 molecule, isotopically natural and deuteriated forms of which have been characterised by their IR spectra; confirmation is afforded by the results of MP2 ab initio and normal coordinate analysis calculations.

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页码：1302 / 1304

页数：3

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