ELECTROCHEMICAL FUNCTIONALIZATION OF ORGANIC-COMPOUNDS BY SMALL MOLECULES

被引：0

作者：

POKHODENKO, VD ^{[1
]}

KOSHECHKO, VG ^{[1
]}

TITOV, VE ^{[1
]}

SEDNEV, DV ^{[1
]}

机构：

[1] LV PISARZHEVSKY PHYS CHEM INST, KIEV, UKRAINE, USSR

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1992年 / 28卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The results of the studies undertaken by the authors as well as published data on the processes of electrochemical incorporation of <<small>> molecules (CO2, SO2, CS2, NO) into organic substrates are presented. Addressed in particular are the reactions of cathodic carboxylation of halogen-containing aliphatic and aromatic compounds, polymers, olefines, of sulfonylation and dithiocarboxylation of freons, of anodic amines nitrozation. The candidate mechanisms of the processes studied and the effect the reagents' nature and the electrolysis conditions have on the reactions' and product composition and yield are con templated.

引用

页码：97 / 114

页数：18

共 87 条

[1] MECHANISM AND KINETIC CHARACTERISTICS OF THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE IN MEDIA OF LOW PROTON AVAILABILITY [J].