Three gas chromatographic methods for the determination of the enantiomeric composition of organic compounds are considered. The previous diastereomeric method and the method based on the use of the stationary chiral phases can be applied only when analytical reagents or sorbents are available. The proposed method consists in determining the enantiomeric composition of organic compounds with the use of achiral bifunctional reagents and does not require any optically active substances. The availability of three independent methods for determining the enantiomeric composition of organic compounds makes it possible to choose the optimum method for the solution of a particular problem.
机构:Department of Analytical Chemistry, Medical Institute for Environmental Hygiene, the Heinrich-Heine-Universität Düsseldorf, D- W-4000 Düsseldorf 1, Auf'm Hennekamp
DUNEMANN, L
HAJIMIRAGHA, H
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机构:Department of Analytical Chemistry, Medical Institute for Environmental Hygiene, the Heinrich-Heine-Universität Düsseldorf, D- W-4000 Düsseldorf 1, Auf'm Hennekamp
机构:Department of Analytical Chemistry, Medical Institute for Environmental Hygiene, the Heinrich-Heine-Universität Düsseldorf, D- W-4000 Düsseldorf 1, Auf'm Hennekamp
DUNEMANN, L
HAJIMIRAGHA, H
论文数: 0引用数: 0
h-index: 0
机构:Department of Analytical Chemistry, Medical Institute for Environmental Hygiene, the Heinrich-Heine-Universität Düsseldorf, D- W-4000 Düsseldorf 1, Auf'm Hennekamp