DEVELOPMENT OF GAS-CHROMATOGRAPHIC METHODS FOR DETERMINING THE ENANTIOMERIC COMPOSITION OF ORGANIC-COMPOUNDS

被引：1
|
作者：
STANKOV, IN [1 ]
TARASOV, SN [1 ]
AGUREYEV, VG [1 ]
BERESNEV, AN [1 ]
LYSENKO, VV [1 ]
LANIN, SN [1 ]
机构：
[1] MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,USSR
来源：
ANALYTICA CHIMICA ACTA | 1991年 / 251卷 / 1-2期
关键词：
GAS CHROMATOGRAPHY; ACHIRAL STATIONARY PHASES; AMINES; AMINO ACIDS; ENANTIOMERS; OPTICAL ISOMERS;
D O I：
10.1016/0003-2670(91)87140-3
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Three gas chromatographic methods for the determination of the enantiomeric composition of organic compounds are considered. The previous diastereomeric method and the method based on the use of the stationary chiral phases can be applied only when analytical reagents or sorbents are available. The proposed method consists in determining the enantiomeric composition of organic compounds with the use of achiral bifunctional reagents and does not require any optically active substances. The availability of three independent methods for determining the enantiomeric composition of organic compounds makes it possible to choose the optimum method for the solution of a particular problem.
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页码：223 / 232
页数：10
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