REGIOSELECTIVE ENZYMATIC ACETYLATION OF METHYL 4,6-O-BENZYLIDENE-ALPHA-D-GLUCOPYRANOSIDE AND 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE

被引:27
作者
CHINN, MJ [1 ]
LACAZIO, G [1 ]
SPACKMAN, DG [1 ]
TURNER, NJ [1 ]
ROBERTS, SM [1 ]
机构
[1] UNIV EXETER,DEPT CHEM,STOCKER RD,EXETER EX4 4RJ,DEVON,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 06期
关键词
D O I
10.1039/p19920000661
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Lipase-catalysed acetylation of 1 furnishes the ester 3 in, 94% yield while, under the same reaction conditions, the isomer 2 affords the ester 5 in 86% yield.
引用
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页码:661 / 662
页数:2
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