THERMOCHEMISTRY OF HYDROGEN MOLYBDENUM BRONZE PHASES HXMOO3

被引：65

作者：

BIRTILL, JJ ^{[1
]}

DICKENS, PG ^{[1
]}

机构：

[1] INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1979年 / 29卷 / 03期

关键词：

D O I：

10.1016/0022-4596(79)90193-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enthalpies of formation of five hydrogen molybdenum bronze phases, HxMoO3 (0 < x < 2), have been determined by solution calorimetry. Values obtained for formation from H2(g) and MoO3(s) at 298.15°K were (kJ mole-1): H0.28MoO3, -18.2 ± 0.5; H0.34MoO3, -22.5 ± 0.6; H0.93MoO3, -56.5 ± 0.8; H1.68MoO3, -83.9 ± 1.6; and H2.0MoO3, -80.4 ± 2.1. The thermodynamic stabilities of these phases are discussed in relation to their observed electrochemical behavior. © 1979.

引用

页码：367 / 372

页数：6

共 18 条

[1]

BESENHARD JO, 1976, J POWER SOURCES, V1, P267

[2] PHASE RELATIONSHIPS IN SYSTEM HXMOO3 (0 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2.0) [J].