PREPARATION AND SPECTROSCOPIC PROPERTIES OF SOME MOLYBDENUM CARBONYL DERIVATIVES OF AMMONIA AND PHOSPHINE

被引：31

作者：

BARLOW, CG

HOLYWELL, GC

机构：

[1] Department of Chemistry, University of Edinburgh, Edinburg, West Mains Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 16卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)89769-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds cis-(PH3)2Mo(CO)4, cis-(PH3)3Mo(CO)3, cis-(NH3)2Mo(CO)4 and cis-(NH3)3Mo(CO)3 have been prepared from cycloheptatrienemolybdenum tricarbonyl and norbornadienemolybdenum tetracarbonyl. The IR spectra of these compounds and of their 2H and 15N analogues have been recorded and assignments made. The NMR spectra are reported and the values of J(PP′) and J(NH) have been obtained. © 1969.

引用

页码：439 / +

共 25 条

[1] TRANSITION-METAL COMPLEXES OF 7-MEMBERED RING SYSTEMS .1. THE CYCLOHEPTATRIENE-METAL COMPLEXES AND RELATED COMPOUNDS [J].