QUADRUPOLAR EFFECTS TRANSFERRED TO SPIN-1/2 MAGIC-ANGLE SPINNING SPECTRA OF SOLIDS

被引：313

作者：

HARRIS, RK ^{[1
]}

OLIVIERI, AC ^{[1
]}

机构：

[1] UNIV NACL ROSARIO,FAC CIENCIAS BIOQUIM & FARMACEUT,RA-2000 ROSARIO,ARGENTINA

来源：

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 1992年 / 24卷

关键词：

D O I：

10.1016/0079-6565(92)80004-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For spin-1/2 nuclei magic-angle spinning fails to completely average dipolar interactions to quadrupolar nuclei. This phenomenon, first noticed for the (C-13, N-14) pair of nuclei, is of common occurrence. The theory is reviewed herein, with emphasis on the perturbation treatment (increasingly valid as the applied magnetic field increases). The information about shielding, dipolar, indirect coupling and quadrupolar interaction tensors, available from the spectra, is discussed. A review is given of applications to a range of nuclear spin pairs.

引用

页码：435 / 456

页数：22

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