Crystal structure of tris(mu-bis[4-[(pyridin-2-ylmethylidene)amino]phenyl}methane-kappa N-4,N ':N '',N ''')dizinc tetrakis(tetrafluoridoborate) acetonitrile trisolvate

被引：0
|
作者：
Alexandru, Maria-Gabriela [1 ]
Dumitru, Florina [1 ]
机构：
[1] Univ Politehn Bucuresti, Fac Appl Chem & Mat Sci, Polizu 1, Bucharest 011061, Romania
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; Znil complex; triple-helical motif;
D O I：
10.1107/S205698901502455X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Zn-2(C25H20N4)(3)](BF4)(4)center dot 3CH(3)CN, consists of one dinuclear ZnIT complex cation with a triple-helical [Zn2L3](4+) motif (L is bis{4-[(pyridin-2-ylmethylidene)amino]phenyllmethane), four BF4- anions and three CH3CN solvent molecules. The Zn center dot center dot center dot Zn separation is 11.3893 (14) angstrom and the ligands wrap around the two Zn-II atoms, forming a triple helix as defined by the Zn N N Zn torsion angles of 104.05 (18), 99.06 (19) and 101.40 (19)degrees. The Zn N(pyridyl) distances in the octahedral ZnN6 coordination sphere are in the range 2.128 (5)-2.190 (5) angstrom and the Zn N(imine) distances are in the range 2.157 (5)-2.277 (5) angstrom.
引用
收藏
页码：M271 / U448
页数：18
相关论文
共 50 条
  • [41] Crystal structure of diaqua[5,10,15,20-tetrakis(4-bromophenyl)porphyrinato-kappa N-4] magnesium
    Amiri, Nesrine
    Nasri, Soumaya
    Roisnel, Thierry
    Simonneaux, Gerard
    Nasri, Habib
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M73 - +
  • [42] Synthesis and Crystal Structure of 4,4'-(4-(1-Naphthyl)-4-phenyl-1,3-butadienylidene)-bis[N,N-diethylbenzenamine]
    LI Xiang-Gao② WU An-Shu XU De-Shun WANG Shi-Rong ZHAO Xue-Ming (Fine Chemicals Department
    Chinese Journal of Structural Chemistry, 2006, (09) : 1063 - 1066
  • [43] Crystal structure of bis(4-nitroaniline-kappa N-1)(5,10,15,20-tetraphenylporphyrinato-kappa N-4) cobalt(III) chloride dichloromethane monosolvate
    Belghith, Yassine
    Mansour, Anissa
    Nasri, Habib
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M312 - +
  • [44] Synthesis and crystal structure of 4,4′-(4-(1-naphthyl)-4-phenyl-1,3-butadienylidene)-bis[N,N-diethylbenzenamine]
    Li Xiang-Gao
    Wu An-Shu
    Xu De-Shun
    Wang Shi-Rong
    Zhao Xue-Ming
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (09) : 1063 - 1066
  • [45] Synthesis, crystal structure and properties of poly[di-μ3-chlorido-di-μ2-chlorido-bis[4-methyl-N-(pyridin-2-ylmethylidene)aniline]dicadmium(II)]
    Theppitak, Chatphorn
    Laksee, Sakchai
    Chainok, Kittipong
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 636 - +
  • [46] Crystal structure of high-spin tetraaquabis(2-chloropyrazine-kappa N-4)iron(II) bis(4-methylbenzene-sulfonate)
    Golub, Bohdan O.
    Shylin, Sergii I.
    Dechert, Sebastian
    Malysheva, Maria L.
    Gural'skiy, Il'ya A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 776 - +
  • [47] Crystal structure of bis(acetonitrile-kappa N)(4,4 '-di-tert-butyl- 2,2 '-bipyridine-kappa N-2, N ') platinum(II) bis(tetra-fluoridoborate) packing as head-to-head dimers
    Joseph, Chris
    Nesterov, Vladimir N.
    Smucker, Bradley W.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 695 - +
  • [48] Crystal structure of chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)-phenyl]porphyrinato-kappa N-4}iron(III)
    Awasabisah, Dennis
    Powell, Douglas R.
    Richter-Addo, George B.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M42 - U204
  • [49] Crystal structure of trichlorido(4 '-ferrocenyl-2,2 ': 6 ', 2 ''-terpyridine-kappa N-3, N ', N '')iridium(III) acetonitrile disolvate
    Davaasuren, Bambar
    Padhy, Harihara
    Rothenberger, Alexander
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M69 - +
  • [50] Syntheses and crystal structures of (R,R)- and (S,S)-bis(acetonitrile-κN)[N,N′-dimethyl-N,N′-bis-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ4N]-iron(II) bis(hexafluoroantimonate)
    Bibik, Yurii S.
    Yulakh, Iryna M.
    Shishkina, Svitlana V.
    Khomenko, Dmytro M.
    Doroshchuk, Roman O.
    Raspertova, Ilona V.
    Lampeka, Rostyslav D.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 1350 - +
12345