TRIAZINE ADDUCTS OF DIMETHYLZINC AND DIMETHYLCADMIUM - X-RAY CRYSTAL-STRUCTURE OF ME2ZN[(CH2NME)3]2

被引：43

作者：

HURSTHOUSE, MB ^{[1
]}

MOTEVALLI, M ^{[1
]}

OBRIEN, P ^{[1
]}

WALSH, JR ^{[1
]}

JONES, AC ^{[1
]}

机构：

[1] EPICHEM LTD,WIRRAL L62 3QF,MERSEYSIDE,ENGLAND

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 09期

关键词：

D O I：

10.1021/om00055a041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of various triazines of the type (CH2NR)3 with dimethylzinc and dimethylcadmium yielded a series of adducts of the type Me2M[(CH2NR)3]2 (where M = zinc or cadmium and R = methyl, ethyl, or isopropyl), of which the methyl derivative of dimethylzinc has proved useful in the growth of high-quality ZnSe by metalloorganic vapor deposition (MOCVD). The X-ray crystal structure of Me2Zn[(CH2NMe)3]2 has been determined and shows the complex to consist of monomeric units of C2-upsilon symmetry. The compound crystallizes in space group Cmcm, a = 13.553 (2) angstrom, b = 7.399 (2) angstrom, and c = 19.738 (4) angstrom, alpha = beta = gamma = 90-degrees.

引用

页码：3196 / 3200

页数：5

共 34 条

[1] THE MOLECULAR-STRUCTURES OF DIMETHYL-ZINC, DIETHYL-ZINC AND DIPROPYLZINC DETERMINED BY GAS-PHASE ELECTRON-DIFFRACTION - NORMAL COORDINATE ANALYSIS AND ABINITIO MOLECULAR-ORBITAL CALCULATIONS ON DIMETHYLZINC
ALMENNINGEN, A
HELGAKER, TU
HAALAND, A
SAMDAL, S
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (02): : 159 - 166
[2] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[3] FACTORS AFFECTING THE DEGREE OF ASSOCIATION OF ALKYL-ZINC AND HYDRIDO-ZINC COMPOUNDS
BELL, NA
MOSELEY, PT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) : 47 - 53
[4] BOERSMA J, 1982, COMPREHENSIVE ORGANO, P823
[5] ADDUCTS OF TRIMETHYLINDIUM WITH AMINE AND PHOSPHINE-LIGANDS - X-RAY CRYSTAL-STRUCTURE OF ME3INNHCME2(CH2)3CME2, ME3INN(CH2CH2)3N AND ME3INNHME(CH2)2NHMEINME3
BRADLEY, DC
DAWES, H
FRIGO, DM
HURSTHOUSE, MB
HUSSAIN, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) : 55 - 67
[6] THE REVERSIBLE ADDUCT FORMATION OF GROUP-III TRIALKYLS WITH RELATIVELY INVOLATILE PHOSPHINES - X-RAY CRYSTAL-STRUCTURES OF (ME3M)2.(PH2PCH2)2 (M = AL, GA, IN) AND (ME3AL)3.(PH2PCH2CH2)2PPH
BRADLEY, DC
CHUDZYNSKA, H
FAKTOR, MM
FRIGO, DM
HURSTHOUSE, MB
HUSSAIN, B
SMITH, LM
[J]. POLYHEDRON, 1988, 7 (14) : 1289 - 1298
[7] BERYLLIUM COMPLEXES WITH BIPYRIDYL AND OTHER CHELATE DONOR GROUPS - EVIDENCE FOR BIPYRIDYL ANION AS DONOR
COATES, GE
GREEN, SIE
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (SEP): : 3340 - +
[8] METALORGANIC CHEMICAL VAPOR-DEPOSITION OF WIDE BAND-GAP II-VI-COMPOUNDS
COCKAYNE, B
WRIGHT, PJ
[J]. JOURNAL OF CRYSTAL GROWTH, 1984, 68 (01) : 223 - 230
[9] MOLECULAR-STRUCTURES OF BIS(3-(DIMETHYLAMINO)PROPYL)ZINC, ZN[(CH2)3N(CH3)2]2, BY X-RAY AND GAS ELECTRON-DIFFRACTION AND BIS(3-MERCAPTOPROPYL)ZINC, ZN[(CH2)3SCH3]2, BY GAS ELECTRON-DIFFRACTION
DEKKER, J
BOERSMA, J
FERNHOLT, L
HAALAND, A
SPEK, AL
[J]. ORGANOMETALLICS, 1987, 6 (06) : 1202 - 1206
[10] TRIS(PYRAZOLYL)HYDROBORATOZINC ALKYL DERIVATIVES - DIRECT COMPARISON OF THE REACTIVITY OF ZN-C AND MG-C BONDS
GORRELL, IB
LOONEY, A
PARKIN, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (03) : 220 - 222

← 1 2 3 4 →