EFFICACIOUS MODIFICATION OF THE MITSUNOBU REACTION FOR INVERSIONS OF STERICALLY HINDERED SECONDARY ALCOHOLS

被引：402
作者：
MARTIN, SF
DODGE, JA
机构：
[1] Department of Chemistry and Biochemistry, The University of Texas, Austin
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 26期
关键词：
D O I：
10.1016/0040-4039(91)80675-V
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical modification of the Mitsunobu protocol for effecting stereochemical inversions of alcohols has been discovered in which use of p-nitrobenzoic acid as the nucleophilic partner results in significantly improved yields with relatively hindered substrates.
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页码：3017 / 3020
页数：4
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