CRYSTAL-STRUCTURES AND CRYSTAL-CHEMISTRY OF THE RETIO3 PEROVSKITES - RE=LA, ND, SM, GD, Y

被引：222

作者：

MACLEAN, DA ^{[1
]}

NG, HN ^{[1
]}

GREEDAN, JE ^{[1
]}

机构：

[1] MCMASTER UNIV,INST MAT RES,HAMILTON L8S 4M1,ONTARIO,CANADA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1979年 / 30卷 / 01期

关键词：

D O I：

10.1016/0022-4596(79)90127-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures of the RETiO3 perovskites, RE = La, Nd, Sm, Gd, and Y, were solved using single-crystal, automated diffractometer techniques. All were found to belong to space group Pbnm and are, therefore, isostructural with the REFeO3 perovskites. The structure of LaTiO3 was solved using a crystal exhibiting a complex twinning. The REO and TiO coordination polyhedra were studied as a function of the RE ion and were compared with those for REFeO3. The major difference in results between RETiO3 and REFeO3 is a more highly distorted TiO octahedron for RE = Gd and Y. © 1979.

引用

页码：35 / 44

页数：10

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