STUDIES OF METAL HALIDES . MAGNETIC PROPERTIES OF SOME MOLYBDENUM(3) BINUCLEAR COMPLEX HALIDES

被引：43

作者：

GREY, IE

SMITH, PW

机构：

[1] Chemistry Department, University of Tasmania, Hobart, TAS, 7001

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 01期

关键词：

D O I：

10.1071/CH9690121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The variation of magnetic susceptibility with temperature for a number of binuclear halide complexes of molybdenum of formula A3IMo2X9 (A = Cs, Et4N, Et3NH; X = Cl, Br) has been studied over the range 90–400°K. The magnetic behaviour is consistent with that expected for magnetically isolated exchange-coupled pairs of molybdenum atoms. The coupling is interpreted as occurring mainly by direct metal-metal interaction rather than superexchange. © 1969, CSIRO. All rights reserved.

引用

页码：121 / &

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