Poly[[mu-bis(4-nitrophenyl) phosphato kappa O-2,O ']sodium]

被引：4

作者：

Gerus, Aleksandra ^{[1
]}

Lis, Tadeusz ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, 14 Joliot Curie St, PL-50383 Wroclaw, Poland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

data-to-parameter ratio = 31.1; meanω(C - C) = 0.001 A °; Rfactor = 0.030; single-crystal X-ray study; T = 100 K; wRfactor = 0.090;

D O I：

10.1107/S1600536813019260

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Na(C12H8N2O8P)], consists of one Na+ cation and one bis(p-nitrophenyl) phosphate anion with a considerable distortion of the phosphate tetrahedron due to the presence of two P-O ester bonds. The anion bridges five Na+ cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. This bridging arrangement leads to the formation of double layers parallel to (001). Adjacent layers are linked through weak C-H center dot center dot center dot O hydrogen bonds.

引用

页码：M464 / +

页数：11

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