SPECTROPHOTOMETRIC METHOD FOR URANIUM DETERMINATION

被引:8
|
作者
SINGH, NSB
MOHAN, SV
BALASUBRAMANIAN, GR
机构
[1] Reactor Research Centre, Department of Atomic Energy, Fuel Reprocessing Development Laboratory, Tamil Nadu, 603102, Kalpakkam
来源
JOURNAL OF RADIOANALYTICAL CHEMISTRY | 1979年 / 52卷 / 02期
关键词
D O I
10.1007/BF02521282
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A very sensitive extraction spectrophotometric method for the analysis of uranium based on the extraction of a uranium-benzoate-crystal violet complex by a mixture of xylene and benzene is described. The absorbance maximum is at 606 nm and molar absorptivity is 4.28·104 l·mol-1·cm-1. The interference due to a number of anions and cations studied without any pre-extraction was found to be within permissible limits. The method has been used for determining uranium in a synthetic solution, i.e., uranium in the presence of various other ions. The interference due to some cations was eliminated by the use of a masking agent (boric acid). © 1979 Akadémiai Kiadó.
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页码:319 / 327
页数:9
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