PHOSPHORUS-NITROGEN COMPOUNDS .64. THE REACTIONS OF HEXACHLOROCYCLOTRIPHOSPHAZATRIENE WITH 2,2-DIMETHYLPROPANE-1,3-DIOL - NUCLEAR-MAGNETIC-RESONANCE STUDIES OF THE PRODUCTS

被引：41

作者：

ALMADFA, HA

SHAW, RA

TURE, S

机构：

[1] Department of Chemistry, Birkbeck College, University of London, London WC1H OPP, Gordon House

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 53卷 / 1-4期

关键词：

2; 2-dimethylpropane-l; 3-diol; ansa compounds; doubly-bridged compound; Hexachlorocyclotriphosphazatriene; n.m.r; studies; spiro compounds;

D O I：

10.1080/10426509008038043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of hexachlorocyclotriphosphazatriene, N3P-, CI6, with 2, 2-dimethylpropane-l, 3-diol yield monospiro-, N3P3CI4[(OCH2)2CMe2], dispiro-, N3P3CI2[(OCH2)2CMe2]2, and trispiroderivatives, N3P3[(OCH2j2CMe2]3 An ansa, N3P3CI4[(OCH2)2CMe2], and a spiro-ansa, N3P3CI2[(OCH2)2CMe2]2 and a doubly-bridged compound, (N3P3CI4)2[(OCH2)2CMe2]2 were also isolated. Product types and relative yields were compared with those arising from propane-1, 3-diol. The yields of ansa products from the reactions of the dimethyl diol seem to be considerably enhanced relative to those of its unmethylated analogue. 31P and 1H n.m.r. spectra are reported. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：333 / 338

页数：6

共 5 条

[1]

ALKUBAISI AH, 1989, HETEROCYCLES, V28, P347

[2] SINGLY, DOUBLY AND TRIPLY BRIDGED POLYAZAHETEROPHANES DERIVED FROM HEXACHLOROCYCLOTRIPHOSPHAZENE, N3P3CL6 [J].