HIGHLY SELECTIVE INSERTION INTO AROMATIC C-H BONDS IN RHODIUM(II) TRIPHENYLACETATE-CATALYZED DECOMPOSITION OF ALPHA-DIAZOCARBONYL COMPOUNDS

被引：71

作者：

HASHIMOTO, S ^{[1
]}

WATANABE, N ^{[1
]}

IKEGAMI, S ^{[1
]}

机构：

[1] TEIKYO UNIV,FAC PHARMACEUT SCI,SAGAMIKO,KANAGAWA 19901,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 20期

关键词：

D O I：

10.1039/c39920001508

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium(II) triphenylacetate, which features a bulky bridging ligand, has been demonstrated to exhibit an exceptionally high order of selectivity for aromatic C-H insertion over aliphatic C-H insertion or cyclopropanation in catalytic decompositions of alpha-diazocarbonyl compounds, thus providing an expedient and general entry to variously substituted indan-2-ones.

引用

页码：1508 / 1510

页数：3

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