HIGHLY SELECTIVE INSERTION INTO AROMATIC C-H BONDS IN RHODIUM(II) TRIPHENYLACETATE-CATALYZED DECOMPOSITION OF ALPHA-DIAZOCARBONYL COMPOUNDS

被引：71
|
作者：
HASHIMOTO, S [1 ]
WATANABE, N [1 ]
IKEGAMI, S [1 ]
机构：
[1] TEIKYO UNIV,FAC PHARMACEUT SCI,SAGAMIKO,KANAGAWA 19901,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 20期
关键词：
D O I：
10.1039/c39920001508
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rhodium(II) triphenylacetate, which features a bulky bridging ligand, has been demonstrated to exhibit an exceptionally high order of selectivity for aromatic C-H insertion over aliphatic C-H insertion or cyclopropanation in catalytic decompositions of alpha-diazocarbonyl compounds, thus providing an expedient and general entry to variously substituted indan-2-ones.
引用
收藏
页码：1508 / 1510
页数：3
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