INSITU MEASUREMENT OF EFFECTIVE GAS DIFFUSIVITY THROUGH HEMATITE PELLETS DURING STEPWISE REDUCTIONS

The Wicke-Kallenbach (W-K) method for effective gas diffusivity measurements could only be used in the vicinity of ambient temperatures. However, in the present study, this technique has been extended to temperatures of about 1273 K through use of a high-temperature cement. This newly developed high-temperature W-K method was applied to in situ measurements of the diffusive and viscous fluxes through hematite pellets during stepwise reductions. When the sam-ple (acid and basic pellets) is reduced, it swells significantly. However, a gas-tight seal between the holder and specimen was successfully maintained by use of a high-temperature cement. This cement, composed mainly of Na2O (20 mass pct) and SiO2, separates into a solid and liquid phase at elevated temperatures. Thus, it can move in the same direction as the expansion of sample and thereby maintain the gas-tight seal. With this new technique, the structural param-eters of gases based on the "dusty gas model" for D'Arcy's flow, Knudsen diffusion, and mo-lecular diffusion were obtained. These parameters were compared with those estimated through pore structure models. © 1990 The Minerals, Metals & Material Society.