RAPID, LOW-ENERGY SYNTHESIS OF LANTHANIDE NITRIDES

被引：49

作者：

FITZMAURICE, JC ^{[1
]}

HECTOR, A ^{[1
]}

ROWLEY, AT ^{[1
]}

PARKIN, IP ^{[1
]}

机构：

[1] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND

来源：

POLYHEDRON | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)86597-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal initiation (400 degrees C) of the reaction between lithium nitride and anhydrous lanthanide halides produces lanthanide nitrides LnN (Ln = Y, La, Pr, Nd, Sm, Eu, Cd, Tb, Dy, Ho, Er, Yb) via a rapid exothermic solid state metathesis reaction. Mixed lanthanide nitrides LnLn'N (LnLn' = PrNd; DyHo; TbDy) are made by reaction of ground powders of LnCl(3) with Li3N. The lanthanide nitrides were characterized by X-ray powder diffraction, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA), FTIR, magnetic moment measurement and microanalysis.

引用

页码：235 / 240

页数：6

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