AQUEOUS METATHESIS POLYMERIZATIONS OF HETEROPOLYCYCLIC ALKENES USING TRANSITION-METAL CHLORIDE CATALYSTS

被引：51

作者：

FEAST, WJ

HARRISON, DB

机构：

[1] Chemistry Department, Durham University, Durham, DH1 3LE, South Road

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/0304-5102(91)85083-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Exo.exo-5,6-bis(methoxymethyl)-7-oxabicyclo[2.2.1]hept-2-ene was polymerised by aqueous emulsion ROMP using the trichlorides of ruthenium, iridium and osmium as catalysts. The inclusion of cis-but-2-ene-1,4-diol or its dimethyl ether in the reaction mixture had a marked effect on both induction times and reactivity, and allowed control of the molecular weight of the product polymers, poly{2,5-[3,4-bis(methoxymethyl)-furanylene]vinylene}s.

引用

页码：63 / 72

页数：10

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