OXIDATIVE DECARBOXYLATION OF CYCLOHEXANE MONOCARBOXYLIC ACID .3. INITIATED OXIDATION

被引：0

作者：

KESZLER, A ^{[1
]}

HEBERGER, K ^{[1
]}

GAL, D ^{[1
]}

COTARCA, L ^{[1
]}

DELOGU, P ^{[1
]}

机构：

[1] RIC CHIM SCPA,RICE FRIULI,I-33050 TORVISCOSA,ITALY

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 53卷 / 02期

关键词：

D O I：

10.1007/BF02073046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mechanism is suggested for the oxidative decarboxylation of cyclohexane monocarboxylic acid initiated by decomposition of H2O2. The process is a non-branching chain reaction. Cyclohexanone and cyclohexanol form in termination reactions.

引用

页码：385 / 390

页数：6

共 5 条

[1]

Emanuel N. M., 1986, MODELLING OXIDATION

[2]

EMANUEL NM, 1973, SOLVENT EFFECTS RADI

[3]

HEBERGER K, 1994, BER BUNSEN PHYS CHEM, V98, P10

[4] OXIDATIVE DECARBOXYLATION OF CYCLOHEXANE MONOCARBOXYLIC ACID AS A DEGENERATE BRANCHING CHAIN-REACTION .1. KINETICS [J].

NEMES, I ;

HEBERGER, K ;

KESZLER, A ;

VASVARI, G ;

GAL, D ;

COTARCA, L ;

DELOGU, P .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1994, 98 (01) :75-81

[5]

RUSSELL GA, 1957, J AM CHEM SOC, V79, P3872

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