STEAM EFFECTS IN 3-WAY CATALYSIS

被引：176
|
作者：
BARBIER-JR, J [1 ]
DUPREZ, D [1 ]
机构：
[1] UNIV POITIERS, CATALYSE & CHIM ORGAN LAB,CNRS,URA 350, 40 AVE RECTEUR PINEAU, F-86022 POITIERS, FRANCE
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 1994年 / 4卷 / 2-3期
关键词：
CARBON MONOXIDE OXIDATION; CERIUM OXIDE; EFFECT OF STEAM ON CATALYST SINTERING; HYDROCARBON OXIDATION; PALLADIUM; PLATINUM; RHODIUM; STEAM REFORMING; 3-WAY CATALYSTS; WATER GAS SHIFT;
D O I：
10.1016/0926-3373(94)80046-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Steam can exert two main effects in three-way catalysis (i) it is a reactant which can oxidize the carbon monoxide by water-gas shift and the hydrocarbons by steam reforming (ii) it is a major component of the exhaust gas which can affect significantly the thermal stability of three-way catalysts. The role of water as a co-reactant in oxidation reactions as well as its role in catalyst sintering are successively reviewed. Most investigations having been carried out with PtRh catalysts, no definite conclusion can be given as far as palladium catalysts are concerned.
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页码：105 / 140
页数：36
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