Crystal structure of di-n-butylbis(eta(5)-pentamethylcyclopentadienyl)-hafnium(IV)

被引：1

作者：

Arndt, Perdita ^{[1
]}

Schubert, Kathleen ^{[1
]}

Burlakov, Vladimir V. ^{[2
]}

Spannenberg, Anke ^{[1
]}

Rosenthal, Uwe ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

基金：

俄罗斯基础研究基金会;

关键词：

crystal structure; hafnocene; n-butyl; racemic twin;

D O I：

10.1107/S2056989015000092

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Hf(C10H15)(2)(C4H9)(2)], reveals two independent molecules in the asymmetric unit. The diffraction experiment was performed with a racemically twinned crystal showing a 0.529 (5): 0.471 (5) component ratio. Each Hf-IV atom is coordinated by two pentamethylcyclopentadienyl and two n-butyl ligands in a distorted tetrahedral geometry, with the cyclopentadienyl rings inclined to one another by 45.11 (15) and 45.37 (16)degrees. In contrast to the isostructural di(n-butyl)bis-(eta(5)-pentamethylcyclopentadienyl)zirconium(IV) complex with a noticeable difference in the Zr-butyl bonding, the Hf-C-butyl bond lengths differ from each other by no more than 0.039 (3) angstrom.

引用

页码：m19 / m20

页数：16

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