THE PROBABILITY OF NONADIABATIC ELECTRON-TRANSFER AS A FUNCTION OF FRICTION

被引：18

作者：

BURSHTEIN, AI

ZHARIKOV, AA

机构：

[1] Institute of Chemical Kinetics and Combustion, Siberian Branch, The USSR Academy of Sciences

来源：

CHEMICAL PHYSICS | 1991年 / 152卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(91)80031-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The probability of non-adiabatic electron transfer is calculated as a function of friction. With the increase of friction, the process speeds up in the beginning and afterwards it slows down. It is shown, that this result peculiar for weak (non-adiabatic) intercenter interaction, essentially differs from its strong (adiabatic) analogue which was first described by Kramers.

引用

页码：23 / 30

页数：8

共 18 条

[1]

ABRAMOWITZ M, 1964, HDB MATH FUNCTIONS, pCH13

[2] NON-MONOTONIC DEPENDENCE OF ELECTRONIC RELAXATION RATE ON SOLVENT VISCOSITY [J].