IONIC ELECTRODEPOSITION OF II-VI AND III-V COMPOUNDS .3. COMPUTER-SIMULATION OF QUASI-REST POTENTIALS FOR M1X1 COMPOUNDS ANALOGOUS TO CDTE

被引：4

作者：

ENGELKEN, RD

机构：

[1] Arkansas State Univ, Jonesboro, AK,, USA, Arkansas State Univ, Jonesboro, AK, USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1987年 / 134卷 / 04期

关键词：

COMPUTER SIMULATION - ION EXCHANGE;

D O I：

10.1149/1.2100581

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The quasi-rest potential (QRP) has been proposed as a key quantity in characterizing compound semiconductor (e. g. CdTe) electrodeposition. This article expands the modeling/simulation representation of CdTe in chemical equilibrium, to calculate two 'QRP's': (i) E//m//1, the mixed potential occurring immediately after current interruption and before any relaxation in double layer ion concentration and significant ion exchange/surface stoichiometry change occur, and (ii) E//m//2, another mixed potential occurring after the double layer ion concentrations have relaxed to their bulk values but still before any significant surface composition change occurs. Significant predictions are discussed.

引用

页码：832 / 837

页数：6

共 11 条

[1]

Antropov L.I., 1972, THEORETICAL ELECTROC

[2] IONIC ELECTRODEPOSITION OF II-VI AND III-V COMPOUNDS .2. CALCULATED CURRENT-DENSITY AND STOICHIOMETRY VS DEPOSITION POTENTIAL CURVES FOR PARAMETER VALUES REPRESENTATIVE OF CDTE AND WITH ONE PARTIAL CURRENT-DENSITY DIFFUSION LIMITED [J].