SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW METHYLENE BRIDGED DOUBLE BUTTERFLY SHAPED COMPLEX [(MU-CH3TE)FE2(CO)6]2[MU-TE(CH2)TE-MU]

被引：25

作者：

MATHUR, P ^{[1
]}

REDDY, VD ^{[1
]}

DAS, K ^{[1
]}

SINHA, UC ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT PHYS,BOMBAY 400076,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 409卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86151-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new methylene bridged compound [(mu-CH3Te)Fe2(CO)6]2[mu-Te(CH2)Te-mu] has been prepared from the reaction at room temperature of Fe3(CO)9(mu-3-Te)2 and excess diazomethane. The compound was subjected to X-ray structural analysis. The crystals were monoclinic, space group C2/c, a = 28.865(10), b = 13.787(7), c = 14.733(4) A, beta = 104.67(2)-degrees, U = 5672 A3, Z = 8, D(c) = 2.637 g cm-3. The structure consists of two '(CO)6Fe2Te(CH3)Te' units connected by a CH2 group.

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页码：255 / 261

页数：7

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