FACILE CLEAVAGE OF A C-C BOND IN A DINUCLEAR NICKEL-COMPLEX

被引:9
作者
LAWRIE, CJ [1 ]
DANKOSH, HE [1 ]
CARPENTER, BK [1 ]
机构
[1] CORNELL UNIV,DEPT CHEM,BAKER LAB,ITHACA,NY 14853
关键词
D O I
10.1016/0022-328X(91)86032-L
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Facile C-C cleavage is demonstrated to occur upon treatment of {(depe)NiBr}2(mu-Z,Z-PhC = CHCH = CPh) with TlPF6. The implications of this reaction for the Reppe cyclotetramerization of alkynes are discussed.
引用
收藏
页码:C7 / C10
页数:4
相关论文
共 5 条
[1]  
BENSON SW, 1976, THERMOCHEMICAL KINET, P309
[2]   REACTION OF (1,4-DIAZABUTADIENE)BIS(ALKENE)NICKEL(0) COMPLEXES WITH ETHYNE [J].
BONRATH, W ;
MICHAELIS, S ;
PORSCHKE, KR ;
GABOR, B ;
MYNOTT, R ;
KRUGER, C .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 397 (02) :255-260
[3]   DIAZADIENES AS CONTROL LIGANDS IN HOMOGENEOUS CATALYSIS .10. ELEMENTARY STEPS IN CATALYTIC 1-ALKYNE COUPLING TO SUBSTITUTED CYCLOOCTATETRAENES [J].
DIERCKS, R ;
STAMP, L ;
KOPF, J ;
DIECK, HT .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (11) :893-894
[4]   IMPACT OF UPWARDLY REVISED DELTA-HFO OF PRIMARY, SECONDARY, AND TERTIARY RADICALS ON MECHANISTIC CONSTRUCTS IN THERMAL REORGANIZATIONS [J].
DOERING, WV .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-PHYSICAL SCIENCES, 1981, 78 (09) :5279-5283
[5]   CATALYTIC AND STOICHIOMETRIC FORMATION OF CYCLOOCTATETRAENES FROM SOLUBLE NICKEL-COMPLEXES [J].
LAWRIE, CJ ;
GABLE, KP ;
CARPENTER, BK .
ORGANOMETALLICS, 1989, 8 (09) :2274-2276