FACILE CLEAVAGE OF A C-C BOND IN A DINUCLEAR NICKEL-COMPLEX

被引:9
|
作者
LAWRIE, CJ [1 ]
DANKOSH, HE [1 ]
CARPENTER, BK [1 ]
机构
[1] CORNELL UNIV,DEPT CHEM,BAKER LAB,ITHACA,NY 14853
关键词
D O I
10.1016/0022-328X(91)86032-L
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Facile C-C cleavage is demonstrated to occur upon treatment of {(depe)NiBr}2(mu-Z,Z-PhC = CHCH = CPh) with TlPF6. The implications of this reaction for the Reppe cyclotetramerization of alkynes are discussed.
引用
收藏
页码:C7 / C10
页数:4
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