Measurement of the thermal energy reaction NO2++NO→NO++NO2

被引:23
作者
Fehsenfeld, F. C. [1 ]
Ferguson, E. E. [1 ]
Mosesman, M. [1 ]
机构
[1] Aeron Lab, ESSA Res Labs, Boulder, CO USA
关键词
D O I
10.1016/0009-2614(69)85071-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reaction NO2+ + NO --> NO --> NO- - NO2 is found to have a rate constant at 300 degrees K of 2.9 x 10(-10) cm(3)/molecule sec. From this observation it is concluded that the reaction is exothermic and that IP(NO2) > > IP(NO) = 9.25 eV.
引用
收藏
页码:73 / 74
页数:2
相关论文
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FEHSENFELD FC, 1966, J CHEM PHYS, V45, P404
[2]  
FERGUSON EE, 1969, IN PRESS ADV ATOMIC, V5
[3]  
Herzberg G., 1966, ELECT SPECTRA POLYAT
[4]   The first ionization potential of nitrogen dioxide [J].
Natalis, P. ;
Collin, J. E. .
CHEMICAL PHYSICS LETTERS, 1968, 2 (02) :79-82