Green Biofuel Production via Catalytic Pyrolysis of Waste Cooking Oil using Malaysian Dolomite Catalyst

被引:23
|
作者
Hafriz, R. S. R. M. [1 ]
Salmiaton, A. [1 ,2 ]
Yunus, R. [1 ]
Taufiq-Yap, Y. H. [2 ]
机构
[1] Univ Putra Malaysia, Fac Engn, Dept Chem & Environm Engn, Upm Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Catalyst Sci & Technol Res Ctr Putra Cat, Upm Serdang 43400, Selangor, Malaysia
来源
BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS | 2018年 / 13卷 / 03期
关键词
Malaysian Dolomite; Base Catalyst; Waste Cooking Oil; Catalytic Pyrolysis; Biofuel;
D O I
10.9767/bcrec.13.3.1956.489-501
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Malaysian Dolomite has shown potential deoxygenation catalyst due to high capacity in removing oxygen compound and produce high quality of biofuel with desirable lighter hydrocarbon (C-8-C-24). The performance of this catalyst was compared with several commercial catalysts in catalytic pyrolysis of Waste Cooking Oil. Calcination at 900 degrees C in N-2 produced catalyst with very high activity due to decomposition of CaMg(CO3)(2) phase and formation of MgO-CaO phase. The liquid product showed similar chemical composition of biofuel in the range of gasoline, kerosene and diesel fuel. Furthermore, Malaysian Dolomite showed high reactivity with 76.51 % in total liquid hydrocarbon and the ability to convert the oxygenated compounds into CO2, CO, CH4, H-2, hydrocarbon fuel gas, and H2O. Moreover, low acid value (33 mg KOH/g) and low aromatic hydrocarbon content were obtained in the biofuel. Thus, local calcined carbonated material has a potential to act as catalyst in converting waste cooking oil into biofuel. Copyright (C) 2018 BCREC Group. All rights reserved
引用
收藏
页码:489 / 501
页数:13
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