catena-Poly[[[aqua(2,2 '-bipyridine-kappa N-2,N ')copper(II)]-mu-furan-2,5-dicarboxylato-kappa O-2(2):O-5]dihydrate]

被引：1
|
作者：
Li, Ya-Feng [1 ]
Xu, Yue [1 ]
Qin, Xiao-Lin [1 ]
Yuan, Yong-Peng [1 ]
Gao, Wen-Yuan [1 ]
机构：
[1] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 14.5; mean ̄(C-C) = 0.003 Å; R factor = 0.034; single-crystal X-ray study; T = 293 K; wR factor = 0.092;
D O I：
10.1107/S1600536812043632
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the title compound, {[Cu(C6H2O5)( C10H8N2)(H2O)]center dot 2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H2O)(2,2 '-bipyridine) units through a furan-2,5-dicarboxylate bridge. The Cu-II atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxylate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine molecule is 83.88 (7)degrees. O-water-H center dot center dot center dot O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).
引用
收藏
页码：M1416 / +
页数：9
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