DIRECT EPOXIDATION OF OLEFINS CATALYZED BY NICKEL(II) COMPLEXES WITH MOLECULAR-OXYGEN AND ALDEHYDES

被引：166

作者：

YAMADA, T ^{[1
]}

TAKAI, T ^{[1
]}

RHODE, O ^{[1
]}

MUKAIYAMA, T ^{[1
]}

机构：

[1] SCI UNIV TOKYO, FAC SCI, DEPT APPL CHEM, SHINJUKU KU, TOKYO 162, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 07期

关键词：

D O I：

10.1246/bcsj.64.2109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a bis(1,3-diketonato)nickel(II) complex, various olefins are directly monooxygenated into the corresponding epoxides on treatment with atmospheric pressure of oxygen or air and aldehydes. Especially, it is noted that bis[1,3-bis(p-methoxyphenyl)-1,3-propanedionato]nickel(II) behaves as an excellent catalyst in the present epoxidation.

引用

页码：2109 / 2117

页数：9

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