DIMETHYLDIOXIRANE EPOXIDATION OF 6,6-DISUBSTITUTED FULVENES

被引：9
|
作者：
ADAM, W
HADJIARAPOGLOU, LP
MEFFERT, A
机构：
[1] Institute of Organic Chemistry, University of Würzburg, D-8700 Würzburg, Am Hubland
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 46期
关键词：
DIMETHYLDIOXIRANE; EPOXIDATION; PENTAFULVENE; REGIOSELECTIVITY; SYNTHESIS;
D O I：
10.1016/S0040-4039(00)93578-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The endocyclic bis-epoxides of various pentafulvenes were readily prepared by epoxidation with excess dimethyldioxirane; stoichiometric expoxidation yielded mixtures of the bis-epoxides and the labile mono-epoxides, but no exocyclic epoxides were observed.
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页码：6697 / 6700
页数：4
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