3,5-BIS(TRIFLUOROMETHYL)PYRAZOLE AND SOME N-SUBSTITUTED DERIVATIVES

被引：41
作者：
CLAIRE, PPK
COE, PL
JONES, CJ
MCCLEVERTY, JA
机构：
[1] School of Chemistry, University of Birmingham, Birmingham, B15 2TT
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 02期
关键词：
D O I：
10.1016/S0022-1139(00)80298-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The pyrazoles [CF3]2C3HN2R [R = H, COPh, C6F5, C6H4NO2-4 and C6H3[NO2]2-2,4] have been prepared in yields ranging from 27% [R = C6F5] to 78% [R = C6H3[NO2]2-2,4] by the reaction between 1,1,1,5,5,5-hexafluoropentane-2,4-dione and the appropriately substituted hydrazine, NH2NHR.
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页码：283 / 289
页数：7
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共 4 条
[1]   CLUSTER CHEMISTRY .48. SOME REACTIONS OF RU3(CO)12 WITH NITROGEN-HETEROCYCLES - X-RAY CRYSTAL-STRUCTURES OF RU3(MU-CO)2(CO)8(BIPY) AND RU3(MU-H)(MU-N2C3H(CF3)2-3,5)(CO)10 [J].
BRUCE, MI ;
HUMPHREY, MG ;
SNOW, MR ;
TIEKINK, ERT ;
WALLIS, RC .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 314 (03) :311-322
[2]   PYRAZOLYL-BRIDGED IRIDIUM DIMERS .7. SYNTHESIS AND PROPERTIES OF BRIDGE-SUBSTITUTED ANALOGS OF [IR(COD)(MU-PZ)]2 (PZH = PYRAZOLE), THE MIXED-BRIDGE COMPLEX [IR2(COD)2(MU-PZ)(MU-FPZ)] (FPZH = 3,5-BIS(TRIFLUOROMETHYL)PYRAZOLE), AND THE MIXED-METAL DIMER [IRRH(COD)2(MU-PZ)2] - CRYSTAL AND MOLECULAR-STRUCTURES OF BIS(CYCLOOCTADIENE)BIS(MU-3-PHENYL-5-METHYLPYRAZOLYL)-DIIRIDIUM(I) (DISSYMMETRIC ISOMER) AND BI(CYCLOOCTADIENE)BIS(MU-3,4,5-TRIMETHYLPYRAZOLYL)DIIRIDIUM(I)R [J].
BUSHNELL, GW ;
FJELDSTED, DOK ;
STOBART, SR ;
ZAWOROTKO, MJ ;
KNOX, SAR ;
MACPHERSON, KA .
ORGANOMETALLICS, 1985, 4 (06) :1107-1114
[3]  
CLAIRE PD, UNPUB
[4]   UBER NITRO-PYRAZOLE NITROSO-PYRAZOLE UND AZOPYRAZOLE [J].
HUTTEL, R ;
BUCHELE, F ;
JOCHUM, P .
CHEMISCHE BERICHTE-RECUEIL, 1955, 88 (10) :1577-1585
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