CAPTO-DATIVE SUBSTITUTION EFFECTS .4. INTRA-MOLECULAR CL,H DISPROPORTIONATION OF AN OXAMIDE CHLORIDE - ENTRY TO IMIDAZOLE DERIVATIVES

被引：14

作者：

JANOUSEK, Z ^{[1
]}

HUYS, F ^{[1
]}

RENE, L ^{[1
]}

MASQUELIER, M ^{[1
]}

STELLA, L ^{[1
]}

MERENYI, R ^{[1
]}

VIEHE, HG ^{[1
]}

机构：

[1] CATHOLIC UNIV LOUVAIN,CHIM ORGAN LAB,B-1348 LOUVAIN LA NEUVE,BELGIUM

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The key step of exhaustive chlorination of tetramethyldithiooxamide 1, which surprisingly led to the new imidazolium salt 4, is Cl,H disproportionation of 2 (capto‐dative substitution) to give 3. Compound 2, precipitates on chlorination of Me2NCCNMe2, but cannot be isolated. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：616 / 617

页数：2

共 8 条

[1] CAPTO-DATIVE SUBSTITUENT EFFECTS .3. SYNTHESIS AND INTRA-MOLECULAR 1,3 CL,H DISPROPORTIONATION OF ETHYL 2,2-DICHLORO-2-(DIMETHYLAMINO)-ACETATE
HUYS, F
MERENYI, R
JANOUSEK, Z
STELLA, L
VIEHE, HG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (08): : 615 - 616
[2] HUYS F, 1979, ANGEW CHEM, V91, P650
[3] HUYS F, 1979, THESIS U LOUVAIN LA
[4] STUDIES ON CHEMOTHERAPEUTICAL DRUGS .6. SYNTHESIS OF NITROIMIDAZOLE DERIVATIVES .1. PREPARATION OF 1-METHYL-4-SUBSTITUTED-5-NITROIMIDAZOLE OR 1-METHYL-5-SUBSTITUTED-4-NITROIMIDAZOLE DERIVATIVES AND THEIR ANTIMICROBIAL ACTIVITY
SHIMADA, K
KURIYAMA, S
KANAZAWA, T
SATOH, M
TOYOSHIMA, S
[J]. YAKUGAKU ZASSHI, 1971, 91 (02): : 221 - +
[5] STABILIZATION OF RADICALS BY CAPTO-DATIVE SUBSTITUTION-C-C ADDITION TO RADICOPHILIC OLEFINS
STELLA, L
JANOUSEK, Z
MERENYI, R
VIEHE, HG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (09): : 691 - 692
[6] STELLA L, 1978, ANGEW CHEM, V90, P741
[7] STELLA L, J PHYS CHEM
[8] 1969, Patent No. 1548390

← 1 →