CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF (BDT-TTP)2CLO4

被引：67

作者：

MORI, T ^{[1
]}

MISAKI, Y ^{[1
]}

FUJIWARA, H ^{[1
]}

YAMABE, T ^{[1
]}

机构：

[1] KYOTO UNIV, GRAD SCH ENGN, DIV MOLEC ENGN, KYOTO 60601, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 10期

关键词：

D O I：

10.1246/bcsj.67.2685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ClO4, BF4, and ReO4 salts of BDT-TTP, 2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene, are isostructural, having uniform columns of the donor molecules. These salts are essentially metallic down to low temperatures, though the resistivity increases to some extent below 200 K. The thermoelectric power and ESR show simple metal-like behavior down to low temperatures.

引用

页码：2685 / 2689

页数：5

共 19 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2] BIS(METHYLTHIO) SUBSTITUTED UNSYMMETRICAL 2,5-BIS(1',3'-DITHIOL-2'-YLIDENE)-1,3,4,6-TETRATHIAPENTALENES [J].

MISAKI, Y ;

NISHIKAWA, H ;

YAMABE, T ;

MORI, T ;

INOKUCHI, H ;

MORI, H ;

TANAKA, S .

CHEMISTRY LETTERS, 1993, (04) :729-732

[3] ETHYLENEDIOXY SUBSTITUTED 2,5-BIS(1',3'-DITHIOL-2'-YLIDENE)-1,3,4,6-TETRATHIAPENTALENES AND THEIR CONDUCTING SALTS [J].

MISAKI, Y ;

NISHIKAWA, H ;

KAWAKAMI, K ;

YAMABE, T ;

MORI, T ;

INOKUCHI, H ;

MORI, H ;

TANAKA, S .

CHEMISTRY LETTERS, 1993, (12) :2073-2076

[4] 2,5-BIS(1',3'-DITHIOL-2'-YLIDENE)-1,3,4,6-TETRATHIAPENTALENE AND ITS RELATED UNSYMMETRICAL DONORS [J].

MISAKI, Y ;

MATSUI, T ;

KAWAKAMI, K ;

NISHIKAWA, H ;

YAMABE, T ;

SHIRO, M .

CHEMISTRY LETTERS, 1993, (08) :1337-1340

[5]

MISAKI Y, 1993, CHEM LETT, P2085

[6]

MISAKI Y, 1993, CHEM LETT, P733

[7]

MISAKI Y, IN PRESS CHEM LETT

[8] THERMOELECTRIC-POWER OF ORGANIC SUPERCONDUCTORS - CALCULATION ON THE BASIS OF THE TIGHT-BINDING THEORY [J].

MORI, T ;

INOKUCHI, H .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1988, 57 (11) :3674-3677

[9] THE INTERMOLECULAR INTERACTION OF TETRATHIAFULVALENE AND BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE IN ORGANIC METALS - CALCULATION OF ORBITAL OVERLAPS AND MODELS OF ENERGY-BAND STRUCTURES [J].

MORI, T ;

KOBAYASHI, A ;

SASAKI, Y ;

KOBAYASHI, H ;

SAITO, G ;

INOKUCHI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (03) :627-633

[10] CRYSTAL-STRUCTURES OF HIGHLY CONDUCTING IODINE COMPLEXES OF TTM-TTP [J].

MORI, T ;

INOKUCHI, H ;

MISAKI, Y ;

YAMABE, T ;

MORI, H ;

TANAKA, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (03) :661-667

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