FIRST TOTAL SYNTHESIS OF (+/-)-OXERINE

被引：26

作者：

AOYAGI, Y

INARIYAMA, T

ARAI, Y

TSUCHIDA, S

MATUDA, Y

KOBAYASHI, H

OHTA, A

KURIHARA, T

FUJIHIRA, S

机构：

[1] TOKYO COLL PHARM,HACHIOJI,TOKYO 19203,JAPAN

[2] JOSAI UNIV,FAC SCI,SAKADO,SAITAMA 35002,JAPAN

来源：

TETRAHEDRON | 1994年 / 50卷 / 48期

关键词：

D O I：

10.1016/S0040-4020(01)85672-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Total synthesis of (+/-)-oxerine (1), a monoterpene alkaloid, starting from 3-bromopyridine (7) is described. The key reaction in this sequence is the samarium iodide (SmI2)-mediated intramolecular cyclization of gamma-ethynyl bromide (4).

引用

页码：13575 / 13582

页数：8

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