ORGANOMETALLIC REACTION-MECHANISMS .10. CONCERNING EFFECT OF MAGNESIUM METAL PURITY AND METHOD OF PREPARATION OF GRIGNARD-REAGENTS ON REACTION WITH KETONES AND NITRILES

被引：26

作者：

ASHBY, EC ^{[1
]}

NEUMANN, HM ^{[1
]}

WALKER, FW ^{[1
]}

LAEMMLE, J ^{[1
]}

CHAO, LC ^{[1
]}

机构：

[1] GEORGIA INST TECHNOL,SCH CHEM,ATLANTA,GA 30332

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1973年 / 95卷 / 10期

关键词：

D O I：

10.1021/ja00791a041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：3330 / 3337

页数：8

共 31 条

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[2]

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[3] DIRECT EVIDENCE FOR REACTIVE SPECIES, AND THEIR REACTION ORDERS, IN ADDITION REACTION OF METHYLMAGNESIUM BROMIDE GRIGNARD TO 2-METHYLBENZOPHENONE [J].

ASHBY, EC ;

LAEMMLE, J ;

NEUMANN, HM .

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[4] GRIGNARD REAGENTS COMPOSITIONS AND MECHANISMS OF REACTION [J].

ASHBY, EC .

QUARTERLY REVIEWS, 1967, 21 (02) :259-&

[5] CONCERNING STRUCTURE OF GRIGNARD REAGENT .2. IN DIETHYL ETHER . RELEVANCE OF GRIGNARD COMPOSITION TO MECHANISM OF ADDITION TO KETONES [J].

ASHBY, EC ;

SMITH, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (20) :4363-&

[6] CONCERNING ADDITION OF GRIGNARD REAGENTS TO KETONES . EVIDENCE FOR A TERMOLECULAR MECHANISM [J].

ASHBY, EC ;

DUKE, RB ;

NEUMANN, HM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (08) :1964-&

[7] ON REACTION OF METHYLMAGNESIUM BROMIDE WITH BENZOPHENONE - EFFECT OF MAGNESIUM METAL PURITY ON KINETIC DATA [J].

ASHBY, EC ;

WALKER, FW ;

NEUMANN, HM .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (06) :330-&

[8]

ASHBY EC, IN PRESS

[9]

ASHBY EC, 1972, J AM CHEM SOC, V94, P5424

[10]

BIKALES NM, 1962, CANAD J CHEMISTRY, V41, P1329

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